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SCR (Selective Catalytic Reduction) is one of the best available technologies for NOx reduction in industrial processes.

Selective Catalytic Reduction (SCR) is an advanced emission control technology designed to significantly reduce nitrogen oxides (NOx) in exhaust gases generated by industrial and other processes.

How does Selective Catalytic Reduction (SCR) work?

The operation of SCR is based on the selective chemical conversion of NOx into nitrogen (N2) and water (H2O) through a catalytic reaction. In general it works by:

  • Injection of a reducing agent and mixing in the SCR reactor: In the Selective Catalytic Reduction process, a reducing agent is injected into the exhaust gas, most commonly ammonia (NH3) or urea (CO(NH2)2) depending on the specific application and conditions. The gases with the reducing agent are mixed in an SCR reactor. It is important to achieve a uniform mixing of the reducing agent with the pollutant gases.

  • Catalytic reaction: In the presence of a specific catalyst, usually a zeolite or a metal-based material, a chemical reaction is initiated. The catalyst accelerates the selective conversion of NOx into nitrogen (N2) and water (H2O) through the following chemical reaction:

4NO + 4NH3 → 4N2 + 6H2O

  • NOx removal: As a result of the catalytic reaction, NOx is converted into nitrogen and water, which significantly reduces NOx emissions in the exhaust gas. Nitrogen and water are non-harmful products that can be safely released into the environment.

An SCR can operate over a wide temperature range, between 200°C and 450°C, and achieve reduction efficiencies of up to 90%.

What are the components of Selective Catalytic Reduction?

A typical Selective Catalytic Reduction consists of several key components:

  • SCR Reactor: Where the chemical reaction between the reducing agent and NOx occurs in the presence of the catalyst.
  • Reducing agent injectors: They introduce a reducing agent, such as ammonia or urea, into the exhaust gases.
  • SCR catalytic converter: The catalytic converter is one of the most important components for a good SCR, with high efficiency and durability. An effective SCR catalyst must have catalytic activity, selectivity and thermal stability to perform the selective conversion of NOx to N2 and H2O, while maintaining its integrity and efficiency over time in a variety of operating conditions and applications. These characteristics are essential for the success of an SCR system in reducing NOx emissions.
  • Control and monitoring unit: Minimise the amount of reducing agent while maximising NOx removal efficiency.

Advantages of Selective Catalytic Reduction for NOx treatment vs. other technologies

  • High Efficiency: SCR offers high NOx reduction efficiency (>90%).
  • Selectivity: It permits the selective conversion of NOx without significantly affecting the conversion of other pollutants, such as CO and VOCs.
  • Flexibility: It can operate in a wide range of operating conditions and applications.

Sectors of application

The wide applicability of Selective Catalytic Reduction in a variety of industrial sectors is due to its effectiveness in NOx reduction, its ability to function in a variety of operating conditions and its compliance with environmental regulations. Some of these sectors are:

  • Power plants: Fossil fuel power plants in particular use SCR systems to reduce NOx emissions.
  • Chemical and petrochemical industry: In industrial processes that generate NOx as a by-product, such as nitric acid production, SCR is used to control and reduce NOx emissions.
  • Gas turbine power generation: Gas turbines used in power generation and cogeneration applications often employ SCR systems to reduce NOx emissions.
  • Steel and metallurgical industry: In industrial foundry operations, steelmaking and metallurgical processes.
  • Steam and heat generation: In industrial boilers and steam generating plants.
  • Incineration and/or waste treatment plants: In waste incineration plants, where municipal and industrial solid waste is burned.
  • Various industries: Several industrial operations, such as the manufacture of chemicals, paper, glass and ceramics, make use of SCR to reduce NOx emissions resulting from combustion processes.